منابع مشابه
Pinned mode in polyacetylene: A distribution of soliton-lattice densities.
The pinned mode in optically excited polyacetylene Is a vibrational envelope with a width of =500 cm centered at 500 cw,". The width of this mode has been attributed to single solitons interacting with a wide range of pinin par etrs. The constancy of the envelope for polyacetylene prepared by disparate methods (Shirakawa and Durham)d Cis-trans ratios, casts doubt on this concept as the underlyi...
متن کاملExcitation Dynamics in Disubstituted Polyacetylene
We studied the excitation dynamics in films of disubstituted polyacetylene, a degenerate groundstate conjugated polymer, using psec transient and steady-state spectroscopies. The polymer is found to support charged and neutral topological soliton excitations concurrent with a strong intrinsic photoluminescence band with quantum efficiency, h . 50%. This leads to stimulated emission in thin film...
متن کاملSoliton Excitations in Polyacetylene and Relativistic Field Theory Models*
A continuum model of a Peierls-dimerized chain, as described generally by Brazovskii and discussed for the case of polyacetylene by Takayama, Lin-Liu and Maki (TLM), is considered. The continuum (Bogliubov-de Gennes) equations arising in this model of interacting electrons and phonons are shown to be equivalent to the static, semiclassical equations for a solvable model field theory of self-cou...
متن کاملElectronic coherence dynamics in trans-polyacetylene oligomers.
Electronic coherence dynamics in trans-polyacetylene oligomers are considered by explicitly computing the time dependent molecular polarization from the coupled dynamics of electronic and vibrational degrees of freedom in a mean-field mixed quantum-classical approximation. The oligomers are described by the Su-Schrieffer-Heeger Hamiltonian and the effect of decoherence is incorporated by propag...
متن کاملIsotope Effect on the Formation Energy of Soliton in t - Polyacetylene
The formation energy of a soliton was derived in the TLM model to be 2∆ 0 /π which is independent of the masses of the polymer atoms. We estimate effects of the electron-phonon coupling on the soliton formation energy, particularly, through modifications of the harmonic oscillations of (CH) groups. A model based on the amplitude mode formalism is used and the electron-phonon coupling is taken i...
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ژورنال
عنوان ژورنال: Proceedings of the National Academy of Sciences
سال: 1980
ISSN: 0027-8424,1091-6490
DOI: 10.1073/pnas.77.10.5626